Hierarchically Organized and Anisotropic Porous Carbon Monoliths
نویسندگان
چکیده
منابع مشابه
Hierarchically porous carbon monoliths with high surface area from bridged polysilsesquioxanes without thermal activation process.
Hierarchically porous carbon monoliths with high specific surface areas have been fabricated by removing nano-sized silica phase from carbon/silica composites pyrolyzed from bridged polysilsesquioxane. This activation method improves the homogeneity between inner and outer parts of the monoliths compared to the conventional thermal activation methods.
متن کاملSetting Directions: Anisotropy in Hierarchically Organized Porous Silica
Structural hierarchy, porosity, and isotropy/anisotropy are highly relevant factors for mechanical properties and thereby the functionality of porous materials. However, even though anisotropic and hierarchically organized, porous materials are well known in nature, such as bone or wood, producing the synthetic counterparts in the laboratory is difficult. We report for the first time a straight...
متن کاملMechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(II) hydroxide-based monoliths.
The synthesis of highly crystalline macro-meso-microporous monolithic Cu3(btc)2 (HKUST-1; btc(3-) = benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)2-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.
متن کاملSynthesis of Porous Carbon Monoliths Using Hard Templates
The preparation of porous carbon monoliths with a defined shape via template-assisted routes is reported. Monoliths made from porous concrete and zeolite were each used as the template. The porous concrete-derived carbon monoliths exhibited high gravimetric specific surface areas up to 2000 m²·g-1. The pore system comprised macro-, meso-, and micropores. These pores were hierarchically arranged...
متن کاملFabrication of porous carbon monoliths with a graphitic framework
Macro/mesoporous carbon monoliths with a graphitic framework were synthesized by carbonizing polymeric monoliths of poly(benzoxazine-co-resol). The overall synthesis process consists of the following steps: a) the preparation of polymeric monoliths by copolymerization of resorcinol and formaldehyde with a polyamine (tetraethylenepentamine), b) doping the polymer with a metallic salt of Fe, Ni o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemistry of Materials
سال: 2020
ISSN: 0897-4756,1520-5002
DOI: 10.1021/acs.chemmater.0c00302